U_R_As_Bs_100 Tight binding - slow off-rate, slow isomerization Equilibrium constants: Ka(A)=1.00e+08 Ka(B)=2.00e+01 Rate constants (1-forward, 2-reverse): k1(A)=1.00e+08 k2(A)=1.00e+00 k1(B)=9.52e-01 k2(B)=4.76e-02 Chemical shifts: w0(R)=150.0 /s (23.9 Hz) w0(R*)=100.0 /s (15.9 Hz) w0(RL)=200.0 /s (31.8 Hz) Base relaxation rates: R2(R)=10.0 /s R2(R*)=10.0 /s R2(RL)=10.0 /s Enthalpy difference from the base state: dH(R)=0.0 dH(R*)=1.0 dH(RL)=-2.0 Total R concentration (*1000): 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Ratio of total L to total R: 0.00 0.20 0.40 0.50 0.60 0.70 0.80 0.90 0.95 1.00 1.05 1.10 1.20